Search results for " radical reaction"

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Electrochemical treatment of aqueous solutions containing one or many organic pollutants at boron doped diamond anodes. Theoretical modeling and expe…

2012

The electrochemical oxidation of organics in water at boron doped diamonds (BDD) was experimentally investigated with the aim to discuss the correlations among the conversion of the pollutants and the instantaneous current efficiency ICE with the operative conditions. A simple theoretical model previously developed for the oxidation of oxalic acid accounting for the cases of mass transfer control, oxidation reaction control and mixed kinetic regimes was adopted and extended to challenge its predictive capability in the case of organics of different nature and in systems with more pollutants. A quite good agreement, between theoretical predictions and experimental data pertaining to the elec…

General Chemical EngineeringRadicalChlorine compoundOxalic acidInorganic chemistryPollution Anodic oxidationElectrochemistryCarboxylic acidRedoxIndustrial and Manufacturing Engineeringchemistry.chemical_compoundElectron transferAOPs; BDD; Diamond anode; Oxygen evolution; Theoretical models Boron; Carboxylic acids; Chlorine compounds; Diamonds; Electrochemical oxidation; Electron transitions; Free radical reactions; Pollution Anodic oxidationMass transferDiamond anodeEnvironmental ChemistryAOPElectron transitionAqueous solutionOxygen evolutionGeneral ChemistrySettore ING-IND/27 - Chimica Industriale E TecnologicaFree radical reactionTheoretical models BoronElectrochemical oxidationchemistryDiamondBDDOxygen evolutionChemical Engineering Journal
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Synthesis of 3-alkyl-4-(cholomethyl)-1-RSO2-1-H-pyrrol-2-(5H)ones, using a sequential ATCR/[1,2] elimination, from 2,2-dichloro-N-(2-chloroallyl)-N-R…

2011

copper cyclization elimination lactams radical reactionSettore CHIM/06 - Chimica Organica
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